Nanoscale Structures of Iron Silicides on NaCl (001) Surface: Self-assembly Synthesis, Morphology, and Optical Properties

Lyaschenko, S.A., Yakovlev, I.A., Andryushchenko, T.A., (...), Varnakov, S.N., Ovchinnikov, S.G.// Nanobiotechnology Reports//

https://doi.org/10.1134/S2635167624602225

We have shown a novel method for the synthesis of iron silicide nanoparticles on a water-soluble NaCl substrate using thermal layer-by-layer deposition of Fe–Si and post-annealing in ultra-high vacuum. The crystal structure, morphology and optical properties of highly dispersed Fe–Si-containing thin films have been studied. As a result, Fe3Si nanoparticles were found to spontaneously form on the surface of salt with an excess of iron in a wide stoichiometric range. We propose a simple method to control the geometric shape of synthesized Fe–Si ferromagnetic nanoparticles by preparation of NaCl surface.


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