Magnetic circular dichroism of Co nanoparticles localized in matrices of various types

Samoshkina, Y., Edelman, I., Chou, H., (...), Stepanova, E., Stepanov, A.// Materialia//

https://doi.org/10.1016/j.mtla.2023.101759

Magnetic and magneto-optical properties of cobalt nanoparticles (Co-NPs) dispersed in a transparent dielectric SiO₂ and semiconductor ZnO matrices have been investigated. Field and temperature dependences of the samples magnetization showed the typical behavior of an ensemble of superparamagnetic particles with a blocking temperature near and below room temperature. The spectroscopy of magnetic circular dichroism (MCD) in the visible and near-infrared light ranges has revealed a significant difference between the behavior of the Co-NPs and a solid Co film. It has been found that the MCD spectrum shape for the Co-NPs does not depend on the matrix type. The room temperature magneto-optical activity of the Co-NPs in the different matrices has been estimated as an indicator for practical applications.